Error 22 means that something interfered with Plays.tv being able to encode properly. We find, more often than not, that this is caused by something on a user's PC and is not a wide-spread issue.
Some known causes of Error 22 have been:
- Graphical mods in the game, like SweetFX
- Out of Date Video Drivers
- In rare cases, if you do not meet the System Requirements
If you feel like this has not helped with your issue, you may also want to try following the instructions for Error 20032 as they can be closely related. LINK
You can also try sending in a ticket with logs attached for us to investigate.